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All-solid-state flexible supercapacitors based on papers coated with carbon nanotubes and ionic-liquid-based gel electrolytes

Identifieur interne : 000223 ( Main/Exploration ); précédent : 000222; suivant : 000224

All-solid-state flexible supercapacitors based on papers coated with carbon nanotubes and ionic-liquid-based gel electrolytes

Auteurs : Yu Jin Kang [Corée du Sud] ; Haegeun Chung [Corée du Sud] ; Chi-Hwan Han [Corée du Sud] ; Woong Kim [Corée du Sud]

Source :

RBID : ISTEX:243E07592330B4D232F0E5112FA0337118C0ECE9

Abstract

All-solid-state flexible supercapacitors were fabricated using carbon nanotubes (CNTs), regular office papers, and ionic-liquid-based gel electrolytes. Flexible electrodes were made by coating CNTs on office papers by a drop-dry method. The gel electrolyte was prepared by mixing fumed silica nanopowders with ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][NTf2]). This supercapacitor showed high power and energy performance as a solid-state flexible supercapacitor. The specific capacitance of the CNT electrodes was 135Fg1 at a current density of 2Ag1, when considering the mass of active materials only. The maximum power and energy density of the supercapacitors were 164kWkg1 and 41Whkg1, respectively. Interestingly, the solid-state supercapacitor with the gel electrolyte showed comparable performance to the supercapacitors with ionic-liquid electrolyte. Moreover, the supercapacitor showed excellent stability and flexibility. The CNT/paper-and gel-based supercapacitors may hold great potential for low-cost and high-performance flexible energy storage applications.

Url:
DOI: 10.1088/0957-4484/23/6/065401


Affiliations:


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<div type="abstract">All-solid-state flexible supercapacitors were fabricated using carbon nanotubes (CNTs), regular office papers, and ionic-liquid-based gel electrolytes. Flexible electrodes were made by coating CNTs on office papers by a drop-dry method. The gel electrolyte was prepared by mixing fumed silica nanopowders with ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][NTf2]). This supercapacitor showed high power and energy performance as a solid-state flexible supercapacitor. The specific capacitance of the CNT electrodes was 135Fg1 at a current density of 2Ag1, when considering the mass of active materials only. The maximum power and energy density of the supercapacitors were 164kWkg1 and 41Whkg1, respectively. Interestingly, the solid-state supercapacitor with the gel electrolyte showed comparable performance to the supercapacitors with ionic-liquid electrolyte. Moreover, the supercapacitor showed excellent stability and flexibility. The CNT/paper-and gel-based supercapacitors may hold great potential for low-cost and high-performance flexible energy storage applications.</div>
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